Reactive pathways in the bromobenzene-ammonia dimer cation radical: Evidence for a roaming halogen radical
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چکیده
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Reactive pathways in the chlorobenzene-ammonia dimer cation radical: new insights from experiment and theory.
Building upon our recent studies of noncovalent interactions in chlorobenzene and bromobenzene clusters, in this work we focus on interactions of chlorobenzene (PhCl) with a prototypical N atom donor, ammonia (NH3). Thus, we have obtained electronic spectra of PhCl···(NH3)n (n = 1-3) complexes in the region of the PhCl monomer S0 -S1 (ππ*) transition using resonant 2-photon ionization (R2PI) me...
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ژورنال
عنوان ژورنال: Journal of Molecular Structure
سال: 2018
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2017.11.122